Search results for "jet-stirred reactor"

showing 5 items of 5 documents

An experimental and kinetic modeling study on the oxidation of 1,3-dioxolane

2021

International audience; The modern catalytic or enzymatic advances allow the production of novel biofuel. Among them, 1,3dioxolane can be produced from formaldehyde and ethylene glycol, both can be obtained from biomass. In this study, the oxidation of 1,3-dioxolane is studied at stoichiometric conditions. The ignition delay times of 1,3-dioxolane/O 2 /inert mixtures were measured in a shock tube and in a rapid compression machine at pressures of 20 to 40 bar and temperatures ranging from 630 to 1300 K. The pressure profiles recorded in the rapid compression machine show a first stage of ignition enlightening the influence of the low temperature chemistry of combustion. Furthermore, mole fr…

Jet-stirred reactor13-dioxolaneMaterials science[SPI] Engineering Sciences [physics]General Chemical EngineeringThermodynamicsCombustion02 engineering and technology010402 general chemistryMole fractionCombustion7. Clean energy01 natural sciencesCatalysislaw.inventionReaction rate[SPI]Engineering Sciences [physics]lawPhysical and Theoretical ChemistryShock tubeComputingMilieux_MISCELLANEOUS[CHIM.ORGA]Chemical Sciences/Organic chemistryMechanical Engineering[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environment021001 nanoscience & nanotechnologykinetic modeling0104 chemical sciencesIgnition system[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry13. Climate actionBiofuels0210 nano-technologyStoichiometryBar (unit)
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An experimental and modeling study of the oxidation of 3-pentanol at high pressure

2019

International audience; High pressure oxidation of 3-pentanol is investigated in a jet-stirred reactor and in a shock tube. Experiments in the reactor were carried out at 10 atm, between 730 and 1180 K, for equivalence ratios of 0.35, 0.5, 1, 2, 4 and 1000 ppm fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were recorded using Fourier transform infrared spectroscopy (FTIR) and gas chromatography (GC). Ignition delay times were measured for 3-pentanol/O2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1000–1470 K and for equivalence ratios of 0.5, 1 and 2. The fuel did not show any low-temperature reactivity…

Jet-stirred reactorMaterials science020209 energyGeneral Chemical EngineeringAnalytical chemistrychemistry.chemical_element02 engineering and technologyMole fraction7. Clean energylaw.invention020401 chemical engineeringKinetics modelinglawignition0202 electrical engineering electronic engineering information engineering0204 chemical engineeringPhysical and Theoretical ChemistryFourier transform infrared spectroscopyShock tubeOlefin fiberArgon[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environmentMechanical Engineering3-pentanolAtmospheric temperature rangeIgnition systemchemistryShock tubeGas chromatographyProceedings of the Combustion Institute
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Oxidation of pentan-2-ol -Part II: Experimental and modeling study

2021

International audience; The oxidation of pentan-2-ol was investigated at high-pressure in a jet-stirred reactor and in a shock tube. Experiments in the JSR were carried out at 10 atm, between 500-1180 K, for five different equivalence ratios of = 0.35, 0.5, 1, 2, 4 and 1000 ppm of fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were quantified using Fourier transform infrared spectrometry (FTIR) and gas chromatography (GC). Ignition delay times were measured for pentan-2-ol/O 2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1070-1460 K and for equivalence ratios of = 0.5, 1 and 2. Ignition delay times of a…

Materials scienceGeneral Chemical Engineeringpentan-2-olAnalytical chemistrychemistry.chemical_element02 engineering and technologyshock tube010402 general chemistryMole fraction01 natural sciences020401 chemical engineeringAb initio quantum chemistry methods0204 chemical engineeringPhysical and Theoretical ChemistryFourier transform infrared spectroscopyShock tubeArgonMechanical Engineering[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environmentdetailed mechanismAtmospheric temperature rangebiofuels0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistrychemistrykineticsjet-stirred reactorGas chromatographyStoichiometry
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A comparative high-pressure jet-stirred reactor study on the oxidation of pentanol isomers: 1-, 2- and 3- pentanol

2018

International audience

[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryJet-stirred reactorpentanol[CHIM.THEO] Chemical Sciences/Theoretical and/or physical chemistryKinetic modelling[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environment[SPI.FLUID] Engineering Sciences [physics]/Reactive fluid environmentComputingMilieux_MISCELLANEOUS
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An experimental and modelling study of the oxidation of 3-pentanol at high pressure

2018

International audience; High pressure oxidation of 3-pentanol is investigated in a jet-stirred reactor and in a shock tube. Experiments in the reactor were carried out at 10 atm, between 730 and 1180 K, for equivalence ratios of 0.35, 0.5, 1, 2, 4 and 1000 ppm fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were recorded using Fourier transform infrared spectroscopy (FTIR) and gas chromatography (GC). Ignition delay times were measured for 3-pentanol/O2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1000–1470 K and for equivalence ratios of 0.5, 1 and 2. The fuel did not show any low-temperature reactivity…

[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryKinetics[SPI]Engineering Sciences [physics][CHIM.THEO] Chemical Sciences/Theoretical and/or physical chemistrypentanoljet-stirred reactor[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environmentignitionShock tube[SPI.FLUID] Engineering Sciences [physics]/Reactive fluid environment3-pentanolkinetic modeling
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